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Practical Pharmaceutical Techniques

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1609086

WARDA SAHAL

5PY015

PRACTICAL PHARMACEUTICAL TECHNIQUES

BLOCK 1: PROTEIN ANALYSIS

Experiment 1: Protein assay using the “Bradford” method

Abstract:

Materials and Methods:

Refer to practical schedule.

Results and Calculations:

PART 1:

Volume used (ml)

Tube number

1

2

3

4

5

6

7

8

Standard protein

0

0.02 (20µl)

0.04 (40µl)

0.06 (60µl)

0.08 (80µ)

0.12 (120µl)

0.16 (160µl)

0.2 (200µl)

Water

0.8

(800 µl)

0.78 (780µl)

0.76 (760µl)

0.74 (740µl)

0.72 (720µl)

0.68 (680µl)

0.64 (640µl)

0.6 (600µl)

Bradford solution

0.2 (200µl)

0.2 (200µl)

0.2 (200µl)

0.2 (200µl)

0.2 (200µl)

0.2 (200µl)

0.2 (200µl)

0.2 (200µl)

Absorbance at 595nm

0

0.051

0.071

0.129

0.166

0.252

0.323

0.413

µ protein/test

0

1

2

3

4

6

8

10

Table 1: Calculating the quantity/test (µg/test) using a standard protein solution of known concentration

The following equation was used to calculate the quantity of protein (µg/test):

[pic 1]

For example, the calculations for the quantity/test for tube number 3 are as follows:

Quantity/test = 50 µg/ml x 0.04 ml

Quantity/test = 2 µg/test

The results in table 1 were used to prepare diagram 1, ‘Standard Calibration Curve 1’ below:[pic 2]

The gradient of the line on the graph can be calculated using the following equation:[pic 3]

[pic 4]

m = 0.325 – 0.08 / 8 – 2

m = 0.041 Absorbance at 595nm per µg protein

PART 2:

Tube

1

2

3

4

5

Dilution factor

1:2

1:4

1:8

1:16

1:32

Unknown protein (µl)

200

200 of tube 1

200 of tube 2

200 of tube 3

200 of tube 4

Water (µl)

200

200

200

200

200

A595

*0.150[pic 5]

0.085

0.042

0.026

0.020

Table 2: Absorbance values obtained from the diluted samples of the unknown protein

* This absorbance value is the most suitable as it is ½ way between the minimum and the maximum absorbance values from the ‘Standard Calibration Curve 1’.

PART 3:

Volume used (ml)

Solution used (µl)

1

2

3

4

5

6

7

8

Unknown protein

100

100

100

100

100

100

100

100

Water

100

100

100

100

100

100

100

100

Bradford solution

200

200

200

200

200

200

200

200

Absorbance at 595nm

0.271

0.266

0.265

0.265

0.269

0.261

0.272

0.263

*µ protein/test

6.56

6.44

6.42

6.42

6.51

6.32

6.59

6.37

Table 3: Calculating the quantity (in µg) of protein in each of cuvettes 1 – 8

* These values were calculated using the y = mx equation where y = A595, m is the gradient which was 0.0413 and x is the unknown. With cuvette 1, the calculations are as follows:

...

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